Professor Kim Jong-baek's team at Yonsei University develops new technology to transfer carbon nanotubes without damage through ice sublimation
A Korean research team has developed a technique that allows the safe transfer of vertically aligned carbon nanotubes at room temperature, significantly enhancing the performance of electronic devices.
Researchers at Yonsei University, led by Professor Kim Jong-baek, have pioneered a method to transfer vertically aligned carbon nanotubes (VACNTs) at room temperature without damaging them. Traditionally, these nanotubes grow at high temperatures exceeding 700°C through chemical vapor deposition, making integration with semiconductor processes that operate below 450°C difficult. The innovative 'ice sublimation transfer process' allows for the transfer of these nanotubes using a thin layer of ice, sidestepping the challenges posed by conventional transfer techniques that involve liquid phases.
The process begins by condensing water vapor onto a cold substrate, forming a uniform layer of ice. The carbon nanotubes grown on this ice layer are temporarily adhered before the ice is sublimated directly from solid to gas in a vacuum, eliminating issues related to capillary forces that previously caused the nanotubes to clump or tilt during the transfer process. This new technique achieved over 95% successful transfer rates, working on substrates ranging from silicon to various metals and polymers while maintaining the vertical structure of the nanotubes.
This breakthrough is significant as VACNTs are next-generation nanomaterials known for their exceptional electrical and thermal conductivity and near-complete light absorption. Their unique 3D structural properties make them ideal for applications in heat-dissipation materials, high-sensitivity infrared absorption layers, and advanced semiconductor devices. The findings, published in the high-impact journal Nature Communications, have the potential to revolutionize the integration of nanomaterials into electronic devices, paving the way for enhanced performance in processors and infrared sensors.