Barcelona SC has made history in the Copa Libertadores by demonstrating remarkable efficiency in penalty shootouts, particularly after their recent match against Argentinos Juniors. Following a draw in aggregate score, the match proceeded to penalties where Barcelona SC exhibited their class, winning 5-4 and solidifying their impressive 80% effectiveness from the spot in the tournament. This statistic places them among the most successful teams in Copa Libertadores history regarding penalties.

The recent series against Argentinos Juniors mirrored previous dramatic encounters typical in knockout football, as Barcelona SC suffered a narrow defeat in the first leg but managed to secure victory by the same margin in the return leg, leading to the inevitable penalty shootout. This consistency in high-stakes scenarios highlights Barcelona SC's confidence and skill under pressure, a crucial element for success in prestigious tournaments like the Copa Libertadores.

Since 1990, Barcelona SC has established a formidable record in penalty shootouts within the Copa Libertadores, achieving eight victories out of ten shootouts they have faced. Their historical success includes memorable matches against notable opponents, reinforcing their reputation as a team capable of handling the immense pressure that accompanies pivotal moments in knockout rounds. Their continued success not only boosts their chances in the current tournament but also enhances their legacy in South American football.